Atomic-scale imaging of ytterbium ions in lead halide perovskites
Wen Xu, Jiamu Liu, Bin Dong, Jindou Huang, Honglong Shi, Xiangxin Xue, Mao Liu- Multidisciplinary
Lanthanide-doped lead halide perovskites have demonstrated great potential for photoelectric applications. However, there is a long-standing controversy about the existence of lanthanide ions, e.g., whether the doping of Ln 3+ is successful or not; the substituting sites of Ln 3+ in lead halide perovskites are unclear. We directly identify the doped Yb 3+ in CsPbCl 3 perovskites by using the state-of-the-art transmission electron microscopy and three-dimensional atom probe tomography at atomic scale. Different from the previous assumptions and/or results, we evidence that Yb 3+ simultaneously replace Pb 2+ and occupy the lattice interstitial sites. Furthermore, we directly observe the cluster phenomenon of CsPbCl 3 single crystal at near atomic scale. Density functional theory modeling further confirms and explains the mechanisms of our findings. Our findings thus provide an atomic-level understanding of the doping mechanism in perovskites and will stimulate a further thinking of the doping effect on the performance of perovskites.