DOI: 10.1039/d3qo01749d ISSN: 2052-4129
Asymmetric copper-catalyzed alkynylallylic dimethylamination
Si-Yuan Luo, Guo-Qiang Lin, Zhi-Tao He- Organic Chemistry
A reliable protocol for asymmetric Cu-catalyzed alkynylallylic dimethylamination is described with the discovery of tetramethyldiaminomethane as a new, stable and convenient surrogate of the dimethylamine nucleophile.