DOI: 10.1039/d3dt04322c ISSN: 1477-9226

Thermodynamics of the Eu(iii)–Mg–SO4–H2O and Eu(iii)–Na–SO4–H2O systems. Part I: solubility experiments and the full dissociation Pitzer model

P. F. dos Santos, A. Lassin, X. Gaona, K. Garbev, M. Altmaier, B. Madé
  • Inorganic Chemistry

A thermodynamic description of complex sulfate systems of relevance for nuclear waste disposal is provided. A full dissociation Pitzer model is derived for the system Eu(

iii
)–Mg/Na–SO4–H2O based on solubility experiments and comprehensive solid phase characterization.

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