Irina V. Vasilenko, François Ganachaud, Sergei V. Kostjuk

Comment on “Lewis acid-surfactant complex catalysed polymerisation in aqueous dispersed media: cationic or radical polymerisation?” by A. Destephen, L. Lezama and N. Ballard, Polym. Chem., 2020, 11, 5757

  • Organic Chemistry
  • Polymers and Plastics
  • Biochemistry
  • Bioengineering

Cationic polymerization catalysed by LASC occurs when radical production is inhibited and at low temperature. Large molar mass distributions obtained in this process call for a mechanism involving preferential coordination of dienic or styrenic monomers by the catalyst.

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