Comment on “Lewis acid-surfactant complex catalysed polymerisation in aqueous dispersed media: cationic or radical polymerisation?” by A. Destephen, L. Lezama and N. Ballard, <i>Polym. Chem.</i>, 2020, <b>11</b>, 5757

doi:10.1039/d3py00661a

Irina V. Vasilenko, François Ganachaud, Sergei V. Kostjuk

Comment on “Lewis acid-surfactant complex catalysed polymerisation in aqueous dispersed media: cationic or radical polymerisation?” by A. Destephen, L. Lezama and N. Ballard, Polym. Chem., 2020, 11, 5757

Organic Chemistry
Polymers and Plastics
Biochemistry
Bioengineering

Cationic polymerization catalysed by LASC occurs when radical production is inhibited and at low temperature. Large molar mass distributions obtained in this process call for a mechanism involving preferential coordination of dienic or styrenic monomers by the catalyst.

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Comment on “Lewis acid-surfactant complex catalysed polymerisation in aqueous dispersed media: cationic or radical polymerisation?” by A. Destephen, L. Lezama and N. Ballard, Polym. Chem., 2020, 11, 5757

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