DOI: 10.1039/d3cp00248a ISSN: 1463-9076

Anomalous π-backbonding in complexes between B(SiR3)3 and N2: catalytic activation and breaking of scaling relations

Tore Brinck, Suman Kalyan Sahoo
  • Physical and Theoretical Chemistry
  • General Physics and Astronomy

Lewis acids of the types B(SiR3)3 and B(GeR3)3 bind N2 and CO with anomalously short and strong B–N or B–C bonds.

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