74 µm PEEK‐Reinforced Sulfonated Poly(phenylene sulfone)‐Membrane for Stable Water Electrolysis with Lower Gas Crossover and Lower Resistance than Nafion N115

Abstract

Polymer electrolyte membrane (PEM) water electrolysis is a crucial technology for green hydrogen production. Hydrocarbon membranes are drawing a lot of attention due to potentially superior properties and the fact that common fluorinated polymers might face a potential ban. This study introduces a sulfonated poly(phenylene sulfone) (sPPS) membrane, reinforced with a poly(ether‐ether‐ketone) (PEEK) mesh. The reinforced membrane induces a drastic increase in dimensional stability, enabling direct anode casting—an essential step toward industrial manufacturing. It further exhibits a significant reduction in water uptake (115% vs 294% for pure sPPS) and a 40% lower H₂‐crossover (0.18 mA cm⁻²) compared to the industry standard N115 (0.31 mA cm⁻²). Due to the lower thickness (74 vs 127 µm) and higher ion exchange capacity (IEC)(1.92 vs 0.89 mmol g⁻¹), the PEEK‐sPPS membrane displays a substantially lower resistance (70 vs 159 mΩ cm² for N115). This directly translates into a voltage reduction of ≈90 mV at 1 A cm⁻² or ≈180 mV at 2 A cm⁻², both typical operating current densities. Finally, PEEK‐sPPS exhibits the longest lifetime shown for hydrocarbon membranes with almost 650 h at 1 A cm⁻² and a low degradation rate (80 µV h⁻¹).