DOI: 10.1039/d6ob00666c ISSN: 1477-0520
Transition-metal-free three-component synthesis of α-tertiary trifluoromethyl phosphonates from CF 3 diazo compounds
Shuangming Zhang, Xianda Wu, Yu-Mei Lin, Shaofeng Wu, Guo Tang, Lei Gong, Ablimit AbdukaderA transition-metal-free, three-component protocol has been developed for the construction of α-trifluoromethylated phosphonates bearing congested, fully substituted carbon centers.