DOI: 10.1039/d3qo01076g ISSN:
Thermal N–O bond heterolysis of TEMPO-CF2CF3 towards trifluoroacetylation of alcohols and amines
Tao Dong, Yihan Tang, Gavin Chit Tsui- Organic Chemistry
A perfluoroalkoxyamine TEMPO-CF2CF3 can be synthesized on gram-scale and it undergoes unusual N–O bond heterolytic cleavage under thermal conditions.