DOI: 10.1039/d3ob01055d ISSN:
Theoretical mechanistic insights into the electrophilic addition of hydrogen halides to alkynes
Yixiang Chen, Shi Cheng, Chongjie Su, Ning Chen, Jiaxi Xu- Organic Chemistry
- Physical and Theoretical Chemistry
- Biochemistry
Mechanistic and stereoselective insights into the hydrohalogenation of alkynes were investigated by DFT calculations and the stereoselectivity depends on the alkyl/aryl substituents of alkynes and the absence or presence of halides.