DOI: 10.1039/d3sc03553k ISSN:

Studying manganese carbonyl photochemistry in a permanently porous metal–organic framework

Rosemary J. Young, Michael T. Huxley, Lingjun Wu, Jack Hart, James O'Shea, Christian J. Doonan, Neil R. Champness, Christopher J. Sumby
  • General Chemistry

Photo-liberation of CO from a Mn(diimine)(CO)3Br moiety anchored within a permanently porous MOF support is studied. The crystallinity and structural flexibility of the MOF allows crystallographic snapshots of the photolysis products to be obtained.

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