DOI: 10.1039/d3sc03553k ISSN:
Studying manganese carbonyl photochemistry in a permanently porous metal–organic frameworkRosemary J. Young, Michael T. Huxley, Lingjun Wu, Jack Hart, James O'Shea, Christian J. Doonan, Neil R. Champness, Christopher J. Sumby
- General Chemistry
Photo-liberation of CO from a Mn(diimine)(CO)3Br moiety anchored within a permanently porous MOF support is studied. The crystallinity and structural flexibility of the MOF allows crystallographic snapshots of the photolysis products to be obtained.