DOI: 10.1002/ejoc.202300755 ISSN:

Strategies for the Controlled Hydrostannylation of Alkynes

Dean D. Roberts, Mark Gerard McLaughlin
  • Organic Chemistry
  • Physical and Theoretical Chemistry

Organostannanes have represented one of the most widely applied reagents in modern cross‐coupling chemistry and represent a key reagent in the synthesis of a range of pharmaceutically relevant scaffolds. This Concept article summarizes recent advances in approaches to the synthesis of these building blocks in a stereocontrolled and regiocontrolled manner. Particular focus is paid to methods which allow for divergent synthesis of alkenylstannanes and developments in methods which present opportunities for sustainable synthesis..

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