DOI: 10.1002/ejoc.202300755 ISSN:
Strategies for the Controlled Hydrostannylation of Alkynes
Dean D. Roberts, Mark Gerard McLaughlin- Organic Chemistry
- Physical and Theoretical Chemistry
Organostannanes have represented one of the most widely applied reagents in modern cross‐coupling chemistry and represent a key reagent in the synthesis of a range of pharmaceutically relevant scaffolds. This Concept article summarizes recent advances in approaches to the synthesis of these building blocks in a stereocontrolled and regiocontrolled manner. Particular focus is paid to methods which allow for divergent synthesis of alkenylstannanes and developments in methods which present opportunities for sustainable synthesis..