DOI: 10.1039/d6ob00980h ISSN: 1477-0520
Stereoselective transformation of alkynes to ( Z )-β-deuterated vinyl sulfones using phosphoryl radical as a halogen atom transfer agent
Shashikant Tiwari, Shiva Pandey, Mahendra Nath, Diwan S. RawatA one-pot phosphoryl radical-mediated strategy converts alkynes into valuable β-deuterated vinyl sulfones using inexpensive D 2 O under metal-free conditions.