DOI: 10.1039/d3qo00559c ISSN:

Stereoselective synthesis of 1,3- and 1,4-dicarbonyl-alkenes from cyclopropenes in a catalytic zinc system

Jiabin Han, Yu Liu, Xiaoyan Yang, Xuheng Zhang, Yuanhao Zhu, Min Zhao, Gefei Hao, Yaojia Jiang
  • Organic Chemistry

This work describes a dual catalytic system for selective synthesis of α-allyl-1,3-ketoaldehydes and α-vinyl-1,4-ketoaldehydes through cascade reactions of hydroxyl substituted aromatic enaminones with cyclopropenes under zinc promoted conditions.

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