DOI: 10.1039/d6ra03820d ISSN: 2046-2069

Stability and reactivity of Fe-DCA 2D metal–organic frameworks on chemically inert graphene support

Dominik Hrůza, Jakub Planer, Tadeáš Lesovský, Ayesha Jabeen, Jan Čechal, Zdeněk Jakub

Scanning tunneling microscopy, X-ray photoemission spectroscopy, and DFT reveal how gas exposure triggers structural degradation of Fe-DCA on graphene, defining the intrinsic stability limits of this 2D MOF.