DOI: 10.1039/d4nj03532a ISSN: 1144-0546
Spin crossover behaviour of asymmetrical iron(iii ) Schiff base complexes from ethylenediamine
Dawit Tesfaye, Mamo Gebrezgiabher, Jonas Braun, Taju Sani, Abbasher Gismelseed, Tim Hochdörffer, Volker Schünemann, Juraj Kuchár, Juraj Černák, Christopher E. Anson, Madhu Thomas, Annie K. Powell Asymmetrical Fe(
iii
) Schiff base complexes, with N4O2 coordination nature, exhibiting abrupt spin crossover with a wide hysteresis loop of 27 K, were synthesised and characterised by SCXRD, SQUID magnetic measurements and Mössbauer spectroscopy.