DOI: 10.1039/d6qo01177b ISSN: 2052-4129

Solvent controlled palladium-catalyzed β-regioselective hydroamination of allenoates with azole heterocycles

Kaixuan Pan, Xin Bai, Wanshu Wang, Lu Gao, Zhenlei Song, Xiaoxiao Tang

Solvent-controlled Pd-catalyzed regiodivergent hydroamination of allenoates with azoles, affording two distinct β-azole-substituted alkene isomers with high regiocontrol under mild conditions.