DOI: 10.1039/d6dt01628f ISSN: 1477-9226
Series of phosphate nonlinear optical materials containing active metal ions with short cut-off edges
Xiaoqin Ma, Xianmeng He, Jialong Wang, Lei Wu, Xue Yu, Qun Jing, Zhaohui ChenActive Pb 2+ /Cd 2+ cations trigger P–O ring to chain transformation and CS to NCS symmetry breaking to afford NLO phosphates with short cut-off edges.