DOI: 10.3390/en19163871 ISSN: 1996-1073

Research and Application of a Liquid Hydrogen Tank Container Based on a Carbon Fiber Suspension Ring Support

Xiaoxiang Zhou, Hang Hai, Lin Zhao, Lei Liu, Feng Yang, Yisu Hao, Wei Wei

Given that large-scale storage and transportation of liquid hydrogen are key to realizing the hydrogen economy, tank containers have attracted much attention for their flexibility. To minimize evaporation losses, efficient support structures are essential for these liquid hydrogen tank containers. Herein, a carbon fiber-reinforced polymer (CFRP) suspension ring is developed to support the inner vessel of liquid hydrogen tank containers. By using a special resin matrix and optimizing its curing process, the suspension ring capitalizes on a small cross-sectional area and low thermal conductivity, thereby significantly mitigating the cold-bridge heat transferred from the outer vessel to the inner vessel. Experimental results demonstrate that the tensile strength, outgassing rate, and fatigue performance of the suspension ring at both 77 K (liquid nitrogen temperature) and 4 K (liquid helium temperature) can meet the design targets. Notably, its equivalent thermal conductivity was approximately 88% lower than that of a stainless steel structure of the same size. With the integration of this suspension ring into a 40 ft liquid hydrogen tank container, the daily liquid nitrogen evaporation rate was recorded below 0.082%/d. Furthermore, the holding time before the pressure reached 0.14 MPa exceeded 192 h with a 90% liquid hydrogen filling ratio. This work provides key technical support for high thermal insulation, long-endurance liquid hydrogen storage and transportation equipment.

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