DOI: 10.1039/d6cc05682b ISSN: 1359-7345
Reducing aromaticity of a hydrocarbon saddle with four fused heptagons by electron removal
Megan E. McCormack, Yikun Zhu, Zhaohang Lin, Chang Wang, Zheng Wei, Junzhi Liu, Marina A. PetrukhinaChemical oxidation of a saddle-shaped hydrocarbon with four continuous heptagons reduced the core aromaticity but retained negative curvature, as revealed by experimental and theoretical data.