DOI: 10.1055/a-2383-6620 ISSN: 0039-7881

Recent advances in the chemistry and the application of SF5-compounds

Mariam Abd El Sater, Lucas Popek, Nicolas Blanchard, Vincent Bizet

This review article outlines the literature covering last three years on the recent developments of the SF5 chemistry. Recent synthesis methodologies of SF5-containing building blocks are reported. These methods include the synthesis of SF5Cl, its use in pentafluorosulfanylation reactions, and oxidative fluorination reactions. Moreover, the reactivity of SF5-alkynes as versatile platform to access new SF5-compounds is described. Finally, effect of SF5 moiety is highlighted according to its application in different fields such as biological/medicinal chemistry, catalysis and material sciences.

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