DOI: 10.1039/d3sc06918d ISSN: 2041-6520
Reactivity of 1,3-enyne MIDA boronates: exploration of novel 1,2-alkyne shift via gem-difluorination
Samir Manna, Debasis Aich, Subrata Hazra, Shivam Khandelwal, Santanu Panda- General Chemistry
Herein, we report the potential utility of 1,3-enyne MIDA boronates to access diverse gem-difluoro MIDA boronates via novel 1,2-alkyne shift, various novel furan-based BCMs via 5-endo-dig cyclization and iterative coupling partners via hydroboration and diboration reaction.