DOI: 10.1039/d4dt03484h ISSN: 1477-9226
Radical-cation salts of BEDT-TTF with tris-coordinated racemic dysprosium(iii ) and terbium(iii ) anions
Emily Howarth, Jordan Lopez, Joseph O. Ogar, Toby J. Blundell, Hiroki Akutsu, Yasuhiro Nakazawa, Shusaku Imajo, Yoshihiko Ihara, Simon J. Coles, Peter N. Horton, Jeppe Christensen, Lee Martin This paper reports the first BEDT-TTF radical-cation salts with D3 symmetry tris-coordinated racemic lanthanide(
iii
) anions. It is also the first crystallographic determination of the nine-coordinate tris(chelidonato)terbate and -dysprosate anions.