Outline
DOI: 10.1039/d6cp03233h ISSN: 1463-9076
Probing chiral chromatography systems in vacuo: cryogenic ion trap laser spectroscopy of diastereomeric copper(
ii
)-proline-tyrosine complexes
Kien X. Vo, Tomonori Izu, Keisuke Hirata, Masaaki Fujii, Shun-ichi Ishiuchi, Anne Zehnacker IR spectroscopy under cryogenic ion trap conditions shows that the copper II complexes with
l
-proline and
d
-tyrosine contain
l
-proline in its zwitterion form, while no zwitterion is observed when both amino acids have the same absolute configuration.
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