DOI: 10.1039/d6qo01266c ISSN: 2052-4129

Photoinduced selective perfluoroalkylation of aldehydes for the synthesis of perfluoroalkylated alkenes

Yi Chen, Zhen Liang, Sudan Tong, Jianwei Yan, Aifang Wang, Chao Shen, Min Wang, Jiabin Shen

A new photocatalytic radical addition–elimination reaction has been described that allows readily accessible aldehydes, dimethyl sulfoxide and perfluoroalkyl iodides to provide perfluoroalkylated alkenes with good E -stereoselectivities.

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