DOI: 10.1039/d6ob01060a ISSN: 1477-0520

Photoinduced radical Truce–Smiles rearrangement driven by halogen bond interactions

Vivek Kumar, Ananthakrishna Panuganti, Fathima Beevi V, Rositha Kuniyil, Veera Reddy Yatham

A novel photoinduced, halogen-bond-assisted, catalyst-free protocol for the difluoroalkylation of alkenes via a radical Truce–Smiles rearrangement was developed.

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