DOI: 10.1039/d6cp01491g ISSN: 1463-9076

Photodetachment spectra of lanthanide oxide clusters: prevalence and importance of shake-up transitions

Lee M. Thompson, Hrant P. Hratchian, Caroline Chick Jarrold

In photodetachment of lanthanide oxide anions, the departing electron can interact strongly with the electrons in the remnant neutral, causing them to reorganize or become excited in what are known as “shake-up” transitions.

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