DOI: 10.1039/d6gc04113b ISSN: 1463-9262
One-pot synthesis of methyl formate from CO
2
, H
2
and methanol over a Ru(
iii
) solid micellar
Catarina M. De Brito Mendes, Jan Öner, Vitaly V. Ordomsky, Mark Saeys In this study, by systematically varying base, temperature, H 2 partial pressure, solvent polarity and H 2 O content, we identify kinetic and thermodynamic factors that control MF synthesis from CO 2 , H 2 and CH 3 OH over a Ru(
iii
) solid micellar catalyst.