DOI: 10.3390/gels12060558 ISSN: 2310-2861

Nano-Iron (III) Oxide-Doped Poly (Itaconic Acid-Co-Acrylamide)/Sodium Alginate Hydrogel for Saline–Alkali Soil Amelioration and Wheat Growth

Zhaomin Sang, Wenhui Zhang, Qinghua Jia, Jianping Zhang, Huiping Ding, Yaling Lu, Ming Ou

Soil salinization poses a significant global challenge to agriculture and the environment, leading to decreased soil fertility and hindered crop growth. Therefore, the development of effective and environmentally friendly soil improvement strategies is crucial for sustainable agriculture. In this study, a range of eco-friendly, versatile, and highly absorbent hydrogels for soil enhancement were created using itaconic acid (IA) as a hydrophilic monomer. Furthermore, their effectiveness and application in agriculture were thoroughly evaluated. The nano-iron-loaded IA-based hydrogels (nano-iron (III) oxide (nano-Fe2O3)/Poly itaconic acid (PIA)-Acrylamide (AM)/Sodium alginate (SA)) hydrogels demonstrated exceptional water absorption and retention capabilities. They exhibited remarkable soil conditioning properties by leveraging carboxyl groups for electrostatic adsorption of saline ions and the porous structure created by the crosslinked network. These features not only significantly facilitated gradual regulation of pH levels and salinity but also effectively enhanced organic matter in saline–alkali soil. Meanwhile, nano-Fe2O3 simultaneously served to stabilize the hydrogel structure and enhance crop nutrient absorption. Wheat cultivation trials demonstrated that the hydrogels notably enhanced the growth of 7-day-old wheat seedlings. The degradation rates of the hydrogels can be adjusted by varying the IA amount, allowing for the continuous release of small organic molecules to enhance soil quality, aligning with various crop growth cycles. Overall, these hydrogels function as environmentally friendly and versatile soil conditioners, offering significant potential for enhancing agricultural soil quality and expanding into related fields.

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