DOI: 10.1177/10567895261465215 ISSN: 1056-7895

MXene-reinforced Elium ® composites: A comprehensive study on tensile and flexural strengths, fracture toughness, thermal properties and damage mechanisms

Bayram Ünal, Yasin Uslugil, Hasan Ulus, Mürsel Ekrem, Hayrettin Düzcükoğlu

This study reports the synthesis of multilayer Ti 3 C 2 T x MXene through selective etching of Ti 3 AlC 2 and its incorporation into Elium ® thermoplastic resin at loadings of 0.25–1.0 wt.%. The resulting nanocomposites were characterized by scanning electron microscopy (SEM), X-ray diffraction, thermogravimetric analysis/differential scanning calorimetry, and mechanical tests, including tensile (ASTM D638), flexural (ASTM D790), and fracture toughness (ASTM D5045) analyses. The 0.75 wt.% MXene composite exhibited the most balanced performance, achieving a tensile strength of 69.45 MPa, a flexural strength of 110 MPa, and a 31% improvement in fracture toughness over neat Elium ® . These enhancements were attributed to uniform nanofiller dispersion and effective interfacial interaction that facilitates stress transfer and crack deflection. SEM fractography revealed a transition from smooth, brittle fracture surfaces in the neat matrix to rough, branched crack paths in the MXene-filled composites, indicating improved energy dissipation. Overall, MXene/Elium ® nanocomposites showed superior strength, toughness, and thermal stability, highlighting their potential as lightweight and recyclable materials for structural applications in automotive, aerospace, and protective sectors.

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