DOI: 10.1039/d6nj02893d ISSN: 1144-0546
Multidentate cyclotribenzylene–triazole ligand for efficient CuAAC in aqueous–organic media
Alsu Gazalieva, Aliya Galimullina, Elza Sultanova, Ekaterina Tyunikova, Daut Islamov, Konstantin Usachev, Vladimir Evtugyn, Marina Il’ina, Vladimir Burilov, Svetlana Solovieva, Igor AntipinA rigid cyclotribenzylene scaffold preorganizes nine triazole groups for cooperative Cu(
i
) binding and self-assembly into catalytically active aggregates, enabling efficient CuAAC with hydrophobic substrates.