DOI: 10.1039/d4cs00742e ISSN: 0306-0012

Mechanism and stereoselectivity in metal and enzyme catalyzed carbene insertion into X–H and C(sp2)–H bonds

Reena Balhara, Ritwika Chatterjee, Garima Jindal
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This review provides a mechanistic overview of asymmetric Fe, Cu, Pd, Rh, Au and heme-based enzymes catalyzed carbene insertion reactions to construct  C–X (X = O, N, S, etc.) and C–C bonds, focusing on the stereochemical models.

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