Low-Temperature EMF Stability of Mineral-Insulated Thermocouples for Pressurized Water Reactor Core Outlet Temperature Measurement

The core outlet temperature is an important safety parameter for pressurized water reactors (PWRs), and its accurate determination depends on highly reliable thermocouple sensors. In this study, two typical commercial K-type thermocouple alloys (de1 and de2) were used to fabricate mineral-insulated metal-sheathed (MIMS) thermocouples. A comparative severe accelerated aging test at 500 °C for 168 h was performed to investigate electromotive force (EMF) stability under high-temperature exposure conditions. After aging, both alloy types exhibited obvious positive EMF drift, and the maximum drift magnitude appeared at the calibration temperature of 400 °C. The measured irreversible EMF drift of de2 thermocouples was lower than that of de1 thermocouples. For the same de2 alloy, thermocouples fabricated with pre-oxidized thermoelement wires presented smaller irreversible drift than those made of bright wires. Reversible EMF drift and heating–cooling calibration hysteresis were more significant for de1 specimens. Stabilization treatment at 570 °C for 2 h followed by furnace cooling effectively reduced the thermal hysteresis of both alloys during temperature cycling. This study provides straightforward experimental data and practical processing references for optimizing the manufacturing route of nuclear-grade MIMS thermocouples with improved high-temperature EMF stability.