Outline
DOI: 10.1021/acs.inorgchem.6c04425 ISSN: 0020-1669
Ligand Symmetry Modulates Singlet–Triplet Energy Gap for Tunable Luminescence Temperature Sensing Performance
Jun-Reng Wu, Jun-Yi Wu, Zong-Ren Chen, Zhen-Yu Liang, Wan-Tao Chen, Jia-Wen YeAbstract
The influence of reverse intersystem crossing on temperature response is a highly intriguing research topic for TADF materials. In this work, we report three isostructural Cu(I) coordination polymers featuring ligands with different symmetries. We tailor their singlet–triplet energy gap to systematically investigate its impact on temperature-responsive properties.
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