DOI: 10.3390/pr14152509 ISSN: 2227-9717

Large-Scale Physical Simulation of CO2 Hydrate Dissociation and Reservoir Response

Tong Zhang, Xiaolong Song, Jian Liu, Jiuhui Cheng, Liang Yuan

Large-scale physical model experiments play a critical role in understanding the coupled thermo–hydro-mechanical responses during hydrate dissociation. In this study, a specially designed large-scale physical simulation apparatus (effective volume: 1178 L) was employed to investigate the depressurization-induced dissociation behavior of CO2 hydrate, which was used as a model system to simulate the macroscopic response of hydrate-bearing sediments under controlled laboratory conditions. Key reservoir parameters—including temperature, pressure, electrical resistivity, gas production rate, and stratum displacement—were continuously monitored using an integrated array of temperature sensors, pressure transducers, electrical resistivity probes, and displacement meters. During depressurization, the system pressure decreased from 3 MPa to 1 MPa (matching the backpressure), while the internal temperature dropped from 3.5 °C to approximately 1 °C due to the endothermic dissociation of the hydrate. Gas production exhibited a three-stage evolution: an initial slow release, a rapid increase as the dissociation front propagated through the sediment, and a plateau upon completion of hydrate dissociation. Based on the measured gas production and CO2 consumption, the hydrate saturation was estimated to be approximately 0.248. The dissociation process led to measurable sediment settlement, with a maximum vertical displacement of 88.3 mm (approximately 5.88% of the model height). Analysis of the evolution of effective stress indicates that depressurization reduced pore pressure and increased vertical effective stress by approximately 0.55 MPa, while hydrate dissociation weakened the sediment skeleton, jointly causing settlement. This study demonstrates the feasibility of using a large-scale apparatus to capture the coupled processes during hydrate dissociation. It provides benchmark experimental data for validating numerical models of hydrate-bearing sediment behavior. Further validation is required before these results can be extrapolated to CH4 hydrate systems.

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