Landau–Zener–Stückelberg–Majorana Interference in Optical Resonators: A Temporal Coupled-Mode Theory Approach

Landau–Zener–Stückelberg–Majorana (LZSM) interference describes the coherent superposition of nonadiabatic transitions when a quantum system is driven through an avoided crossing, but its classical optical analog remains largely unexplored. This work establishes an optical-resonator-based platform for exploring LZSM interference in atomic polarization dynamics using temporal coupled-mode theory. By exploiting the formal correspondence between the cavity mode and atomic polarization in a weakly driven two-level system (TLS), exact analytical solutions are derived for linear frequency sweeps and sinusoidal modulation. The results reveal that the Landau–Zener transition of atomic polarization occurs even when the input frequency transiently sweeps across resonance. The finite temporal memory inherent in the cavity response gives rise to Stückelberg interference, manifesting as oscillations in transmission and cavity energy. The dependence of the interference pattern on sweep rate, linewidth, and modulation is systematically analyzed, and a non-monotonic behavior of oscillation amplitude versus the cavity linewidth is identified. Furthermore, the conventional critical coupling concept is reexamined in the nonadiabatic regime, where counterintuitively the deepest transmission dip occurs under over-coupling rather than critical coupling. Finally, an inverse-design approach engineering both the amplitude and frequency of the input frequency is introduced to tailor the LZSM interference pattern. Our results provide a new platform to all-optical simulation of complex quantum interference.