DOI: 10.1039/d6gc02210c ISSN: 1463-9262
Kinetically guided on-demand m CPBA generation enables safe and sustainable light-driven synthesis of Davis reagents
Muthu Karuppasamy, Mohamed S. H. Salem, Kwangkyun Jang, Mitsuhiro Arisawa, Masayuki Kirihara, Shinobu TakizawaOn-demand in situ generation of m CPBA under sunlight enables efficient oxidation of N -sulfonyl imines. Kinetic studies confirm no m CPBA accumulation, minimizing peracid-handling risks and providing a safe and sustainable protocol to Davis reagents.