DOI: 10.1039/d6dt02275h ISSN: 1477-9226

Ion-pair complexes of oxidorhenate( v ) with phenolate–oxazoline ligands: synthesis, solvatochromism and catalytic properties

Tobias A. Doliner, Anna M. Schlegl, Kristin Kogler, Milan Milovanović, A. D. Boese, Ferdinand Belaj, Antoine Dupé, Peter E. Hartmann, Jörg A. Schachner

Ion pairing in oxidorhenium(

v
) complexes triggers striking solvatochromism via ion-pair charge transfer (IPCT), a phenomenon mechanistically elucidated through combined experiment and theory.

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