DOI: 10.1039/d6cp03474h ISSN: 1463-9076

Infrared spectroscopic and theoretical characterization of hemibond stability in microhydrated [H 2 O–X] + (X = Kr and Xe) radical cation clusters

Tatsuki Hosoda, Asuka Fujii

Hemibonded [H 2 O–X] + (X = Kr and Xe) clusters respond differently to microhydration. The hemibond in [H 2 O–Kr] + is disrupted, whereas that in [H 2 O–Xe] + remains intact.

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