Influence of La Geria-Inspired Microstructures (LGMs) on the Corrosion Behavior of Super Duplex Stainless Steel in Seawater and Desalination Brine Environments

Super duplex stainless steels are widely used in seawater desalination plants due to their high mechanical strength and excellent corrosion resistance in chloride-rich environments. However, during reverse osmosis processes, the salinity of the reject stream increases progressively, generating concentrated brines with concentrations close to 7 wt.% NaCl, which represent a chloride-rich service environment that may affect passive film stability and promote localized corrosion. This study investigates the effect of novel La Geria-inspired microstructures (LGMs) generated by laser surface texturing on the microstructure, microhardness, and electrochemical behavior of UNS S32750 super duplex stainless steel in 3.5 wt.% and 7.0 wt.% NaCl solutions, simulating seawater and concentrated desalination brine. Electrochemical results show that textured surfaces exhibit improved corrosion resistance, with more stable corrosion potentials, lower corrosion current densities, and higher impedance values. Microhardness measurements revealed a homogeneous mechanical response, confirming that laser texturing does not alter the mechanical integrity of the material. Microstructural observations showed reduced surface degradation and improved preservation of the duplex ferrite–austenite structure in textured samples after exposure to chloride solutions. These findings demonstrate that biomimetic laser surface texturing enhances corrosion resistance by modifying interfacial conditions and stabilizing the passive film, providing experimental evidence of the beneficial effect of LGMs in aggressive desalination environments.