DOI: 10.1039/d6el00097e ISSN: 3033-4063

Influence of chloride on the crystallization and photostability of mixed-halide FAPbBr 3− x Cl

Laura Bellini, Guus J. W. Aalbers, Simon V. Quiroz Monnens, Nick R. M. Schipper, Willemijn H. M. Remmerswaal, Lana M. Kessels, Christ H. L. Weijtens, Martijn M. Wienk, René A. J. Janssen

Chloride widens the bandgap of FAPbBr 3− x Cl x perovskites and retards crystallization, resulting in larger grains but reduced light stability. Cs improves photostability, while F-PEACl raises the efficiency to 7.3% at a 2.38 eV optical bandgap.

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