Impedance Spectroscopy of Hybrid Structures Based on Nanostructured Porous Silicon and Porous Hierarchical Nickel Oxide Nanoparticles

A technological approach to the formation of a 3D nanocomposition material based on hierarchical porous nickel oxide nanoparticles incorporated into porous silicon with a dendritic porous structure is proposed. Porous silicon was used as a 3D porous template, in the presence of which porous hierarchical nickel oxide nanoparticles were synthesized using a “green” synthesis method followed by annealing in an oxygen-containing atmosphere. The resulting materials were characterized using scanning electron microscopy, transmission electron microscopy, X-ray spectral microanalysis, X-ray diffraction, and the BET method. The potential of a developed composition based on porous hierarchical nickel and silicon oxide nanoparticles to enhance the sensitivity of adsorption gas sensors was assessed using impedance spectroscopy in the presence of a probe gas (isopropanol). Gas sensitivity measurements were conducted at room and elevated temperatures in the frequency range from 100 Hz to 500 kHz. Differences in the dependences of the real part of impedance on the imaginary part were revealed for the porNiO-porSi composition in Nyquist coordinates. The results are discussed in terms of percolation theory and fractal organization.