DOI: 10.1039/d4dt02628d ISSN: 1477-9226
Hypoxia-activated dissociation of heteroleptic cobalt(iii ) complexes with functionalized 2,2′-bipyridines and a model anticancer drug esculetin
Ekaterina Khakina, Igor Nikovskiy, Kirill Spiridonov, Valentin Novikov, Evgenia Antoshkina, Dzhuliia Dzhalilova, Marina Diatroptova, Alina Martyanova, Alexey Rodionov, Yulia V. Nelyubina The substituent's Hammett parameter correlates linearly with electrochemical reduction potentials and rates of hypoxia-activated dissociation of cobalt complexes with esculetin.