Outline
DOI: 10.1039/d6re00188b ISSN: 2058-9883
Hydrosoluble Pd(MesSO 3 )(TPPTS) catalyst for highly active and selective telomerization of 1,3-butadiene with methanol
Muhammad Sajjad, Sivadasan Dharani, Karuppathevan Ramki, Salman Qadir, Muhammad Kamran, Shao-Tao BaiTelomerization of 1,3-butadiene with methanol is efficiently catalyzed by in situ generated Pd(NHC)(TPPTS) system, providing 1-methoxy-2,7-octadiene (1-MOD) with 99.1% linear selectivity, 35 913 TON, and remarkable tolerance to water (up to 33% v/v).
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