DOI: 10.3390/mining6030060 ISSN: 2673-6489

Hydrogen Underground Storage in Lined Rock Caverns in Southern Ontario, Canada

Yu Liang, Yutong Chai, Xingyu Wang, Samantha Espley, Shunde Yin

Lined rock caverns offer a promising option for underground hydrogen, helping to mitigate renewable intermittency and enhance system stability. Considering the geological characteristics of hard rock formations in Southern Ontario, Canada, this study establishes a thermo–gas–mechanical coupled framework that incorporates hydrogen mass and energy evolution in the cavern, gas–wall convective heat exchange, dynamic cavern-volume feedback, and the deformation behaviour of the sealing layer, concrete lining, and surrounding rock. The influences of cavern geometry, sealing material, and in situ stress on the short–term thermodynamic and mechanical responses are further examined. The results show that hydrogen temperature and pressure exhibit clear stage–dependent evolution during the charging–storage–discharging cycle. The comparison between the first and 20th operating cycles indicates that repeated operation mainly causes a moderate adjustment of the cyclic thermal state and temperature–pressure baseline, without changing the overall stage–dependent response pattern. During charging, temperature and pressure increase simultaneously; during storage, both gradually decrease as thermal energy is transferred to the cavern wall; and during discharging, expansion causes pronounced cooling and depressurization, followed by gradual recovery driven by heat transfer from the surrounding rock. Cavern geometry significantly affects stress redistribution around the cavern. The circular cavern shows a relatively uniform stress distribution, whereas the arched cavern is more prone to local stress concentration near the sidewall–floor transition zone. The sealing material mainly influences gas temperature fluctuations through its thermal conductivity. The fibre–reinforced plastic (FRP) sealing layer amplifies thermal fluctuations during cyclic operation, whereas the steel sealing layer promotes heat dissipation through the lining and surrounding rock, thereby moderating cavern–gas temperature variations. In situ stress difference further controls the directional distribution of stresses around the cavern. As the minimum horizontal principal stress increases, compressive stress concentration at the crown and invert becomes stronger, while relative stress release occurs near the sidewalls. These findings provide a thermo–mechanical basis for preliminary cavern–geometry design, comparison of sealing–layer thermal performance, and assessment of in situ stress adaptability for lined rock cavern hydrogen storage in Southern Ontario.

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