DOI: 10.1039/d3dt01958f ISSN: 1477-9226
Homoleptic complexes of isocyano- and diisocyanobiazulenes with a 12-electron, ligand-based redox capacity
Patrick T. Connelly, Jason C. Applegate, David A. Maldonado, Monisola K. Okeowo, Wade C. Henke, Allen G. Oliver, Cindy L. Berrie, Mikhail V. Barybin- Inorganic Chemistry
The redox non-innocent 2-isocyano-6,6′-biazulenic ligand platform exhibits reduction potential inversion and offers construction of molecular organometallic electron reservoirs with 2e−-per-ligand reversible redox capacity.