DOI: 10.1039/d6qi01422d ISSN: 2052-1553
Hierarchical assembly for resolving enantiomeric metal clusters
Haipeng Fang, Xiaojiao Yang, Yanlan Wang, Jianyu Wei, Fangyu Fu, Zhiping Zheng, Manzhou ZhuA ligand-exchange-driven hierarchical coordination assembly strategy is proposed for spontaneous resolution of Ag clusters, which proceeds by eliminating heterochiral supramolecular interactions and reinforcing homochiral coordination interactions.