Glass Additive Manufacturing Technologies: Approaches, Applications, and Challenges

Glass additive manufacturing (AM) is a developing technology, particularly in comparison to metals and polymers, both of which have had their processes and applications extensively studied. Its potential lies in fabricating complex, even micrometric, geometries that are difficult or impossible to achieve via traditional molding, as well as in producing components with unique optical properties. The diversity of AM techniques, alongside the challenges associated with the high melting point, rheological control, and fragility of glass, necessitates a comprehensive analysis of current developments. Accordingly, this review presents a systematic review, conducted in accordance with the PRISMA protocol, of recent literature regarding AM technologies that fabricate glass via particle fusion to form solid components. This review explicitly excludes techniques utilizing glass fibers as reinforcement, as that constitutes a separate field of inquiry. The results demonstrate sustained growth within the field, with a predominance of technologies based on photopolymerization and ink extrusion, both of which offer high resolution and microstructural control. Ultimately, this review establishes the current state of the art, identifying critical challenges and emerging lines of research to guide future development. It is intended to serve as a foundational reference for researchers and professionals seeking to initiate or expand their work in glass AM.