DOI: 10.1039/d3cc03084a ISSN:
Fused metallacyclopropenes from alkynylphenols
Bingjie Fu, Wei Bai, Yue Zhao, Yang Li, Wenfeng Jiang- Materials Chemistry
- Metals and Alloys
- Surfaces, Coatings and Films
- General Chemistry
- Ceramics and Composites
- Electronic, Optical and Magnetic Materials
- Catalysis
Metallabenzofuran-fused osmacyclopropene complexes are obtained from the reactions of OsCl2(PPh3)3 with 2-alkynylphenols. Paramagnetic alkyne-coordinated phenolate Os complexes are proposed to be the key intermediates.