DOI: 10.1039/d6dt01497f ISSN: 1477-9226
From oxido-bridged dimers to hydrogen-bonded assemblies: steric control of self-assembly in
cis
-dioxovanadium(
v
) Schiff-base complexes
Eric J. Shepard, Andrew C. Bates, Chris J. Chang, Avery M. Gibson, Adam R. Miller, Navamoney Arulsamy, Urszula K. Komarnicka, Craig C. McLauchlan, Debbie C. Crans Steric control redirects cis -dioxidovanadium(
v
) Schiff-base self-assembly from covalent O–V–O–V dimers to hydrogen-bonded dimeric and tetrameric supramolecular assemblies governed by the vanadium coordination chemistry.