DOI: 10.1039/d6ra03855g ISSN: 2046-2069

First-principles study of defect chemistry and thermoelectric performance of CaMg 2 Sb 2

Shuai Zhang, Yuan Liu, Wenjing Qiu, Juan Li, Qidong Wang, Kai Han, Xiaole Qiu, Bing Sun

Compared with p-type transport, n-type CaMg 2 Sb 2 is predicted to exhibit a maximum zT of ∼1.52 at 725 K, with the Ca-rich and Mg-rich growth conditions favoring its transport performance.

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